13C NMR spectra of stereoisomeric derivatives of bicyclo[2.2.1]-hept-5-ene and 3-oxatricyclo[3.2.1.02,4]octane

  • A. S. Shashkov
  • E. G. Cherepanova
  • L. I. Kas'yan
  • L. Yu. Gnedenkov
  • M. F. Bombushkar'
Physical Chemistry
  • 65 Downloads

Conclusions

  1. 1.

    Stereoisomeric derivatives of bicyclo[2.2.1]hept-5-ene and 3-oxatricyclo[3.2.1.02,4]-octane were synthesized.

     
  2. 2.

    The13C NMR spectra of the bicycloheptanes and the corresponding epoxide compounds were analyzed and compared with the spectra of the hydrogenated analogs.

     
  3. 3.

    The α, β, γ, and δ effects of substituents at C(2) in these series of compounds were compared and discussed.

     
  4. 4.

    Methods for analyzing the13C NMR spectra of these compounds using the α, β, γ, and δ effects of substituents at C(2) were discussed.

     

Keywords

Epoxide Octane Epoxide Compound Bicycloheptanes 

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • A. S. Shashkov
    • 1
    • 2
  • E. G. Cherepanova
    • 1
    • 2
  • L. I. Kas'yan
    • 1
    • 2
  • L. Yu. Gnedenkov
    • 1
    • 2
  • M. F. Bombushkar'
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR
  2. 2.Dnepropetrovsk State UniversityUSSR

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