Conclusions
-
1.
We synthesized and characterized the binuclear heterometallic complexes of some Group VIB metal carbonyls containing π-pyrrolyltricarbonylmanganese (PTM) as the p-ligand.
-
2.
The p-coordination of PTM with the W(CO)5 fragment leads to retarding the rate of the acid isotopic hydrogen exchange of the pyrrolyl ligand by nearly 40 times when compared with the starting PTM, in which connection the reactivity of the α and β positions remains practically the same.
-
3.
It was shown by the IR spectroscopy method that in acid medium the complex (CO)5W· PTM is protonated at the W atom, which testifies to the high donor properties of PTM as a p-ligand.
Similar content being viewed by others
Literature cited
N. I. Pyshnograeva, V. N. Setkina, V. G. Andrianov, Yu. T. Struchkov, and D. N. Kursanov, J. Organomet. Chem.,128, 381 (1977).
N. I. Pyshnograeva, V. N. Setkina, V. G. Andrianov, Yu. T. Struchkov, and D. N. Kursanov, J. Organomet. Chem.,157, 431 (1978).
N. D. Pyshnograeva, V. N. Setkina, V. G. Andrianov, Yu. T. Struchkov, and D. N. Kursanov, J. Organomet. Chem.,186, 331 (1980).
V. N. Setkina, N. I. Pyshnograeva, P. V. Petrovskii, N. E. Kolobova, and D. N. Kursanov, Dokl. Akad. Nauk SSSR,220, 123 (1975).
C. S. Kraihanzel and F. A. Cotton, Inorg. Chem.,2, 533 (1963).
B. V. Lokshin, V. I. Zdanovich, N. K. Baranetskaya, V. N. Setkina, and D. N. Kursanov, J. Organmet. Chem.,37, 331 (1972).
B. V. Lokshin, A. G. Ginzburg, V. N. Setkina, D. N. Kursanov, and I. B. Nemirovskaya, J. Organomet. Chem.,37, 347 (1972).
N. V. Kislyakova, N. I. Pyshnograeva, V. F. Sizoi, N. E. Kolobova, V. N. Setkina, and D. N. Kursanov, Dokl. Akad. Nauk SSSR,212, 367 (1973).
Yu. N. Sukharev and Yu. S. Nekrasov, Org. Mass Spectrom.,11, 1239 (1976).
Author information
Authors and Affiliations
Additional information
See [3] for Communication 2.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 654–657, March, 1981.
Rights and permissions
About this article
Cite this article
Pyshnograeva, N.I., Setkina, V.N. & Kursanov, D.N. π Complexes as ligands in compounds of the transition metals. Russ Chem Bull 30, 496–499 (1981). https://doi.org/10.1007/BF00949604
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00949604