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Oxidation of polyunsaturated compounds initiated by dicyclohexyl peroxydicarbonate

  • Z. S. Kartasheva
  • O. T. Kasaikina
  • A. B. Gagarina
Physical Chemistry
  • 20 Downloads

Conclusions

  1. 1.

    Dicyclohexyl peroxydicarbonate reacts directly with β-carotene and retinyl acetate without the formation of free radicals. The rate constants of these reactions have been determined.

     
  2. 2.

    The reactivity of polyenes with respect to oxidation by peroxy oxygen increases as the length of the chain of conjugation increases.

     

Keywords

Oxidation Oxygen Acetate Free Radical Peroxy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    A. B. Gagarina, O. P. Kasaikina, and N. M. Émanuél', Dokl. Akad. Nauk SSSR,212, 399 (1973).Google Scholar
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    E. Manzoor and E. E. Cole, Nature,203, 186 (1964).Google Scholar
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    Z. S. Kartasheva and A. B. Gagarina, Izv. Akad. Nauk SSSR, Ser. Khim., 790 (1980).Google Scholar
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    O. T. Kasaikina, Z. S. Kartasheva, and A. B. Gagarina, Izv. Akad. Nauk SSSR, Ser. Khim., 536 (1981).Google Scholar
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    N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Liquid-Phase Hydrocarbon Oxidation Chain Reactions [in Russian], Nauka, Moscow (1965).Google Scholar
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    E. T. Denisov and L. I. Denisova, Dokl. Akad. Nauk SSSR,157, 907 (1964).Google Scholar

Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • Z. S. Kartasheva
    • 1
  • O. T. Kasaikina
    • 1
  • A. B. Gagarina
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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