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Reaction of 1,2,3-triphenylcyclopropene with free bromine in solvents of variable polarity

  • G. A. Kudryavtseva
  • O. A. Nesmeyanova
Organic Chemistry

Conclusions

The three-membered ring of 1,2,3-triphenylcyclopropene is retained during radical bromination and is opened during electrophilic bromination, in which connection the character of the solvent determines either the radical or electrophilic mechanism of the reaction and the path of stabilizing the bromoallyl cation.

Keywords

Bromine Variable Polarity Radical Bromination Free Bromine Electrophilic Mechanism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • G. A. Kudryavtseva
    • 1
  • O. A. Nesmeyanova
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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