Reaction of 1,2,3-triphenylcyclopropene with free bromine in solvents of variable polarity

  • G. A. Kudryavtseva
  • O. A. Nesmeyanova
Organic Chemistry


The three-membered ring of 1,2,3-triphenylcyclopropene is retained during radical bromination and is opened during electrophilic bromination, in which connection the character of the solvent determines either the radical or electrophilic mechanism of the reaction and the path of stabilizing the bromoallyl cation.


Bromine Variable Polarity Radical Bromination Free Bromine Electrophilic Mechanism 
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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • G. A. Kudryavtseva
    • 1
  • O. A. Nesmeyanova
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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