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1,5- and 1,9-migration of hydrogen during telomerization of propylene with dimethyl acetal

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The telomerization of propylene with dimethyl acetal leads to the formation of two series of telomers, and specifically acetals and acetates.

  2. 2.

    The formation of the acetates is due to rearrangement of the growing radicals with a 1,5- and 1,9-migration of hydrogen. The transition from ethylene to propylene leads to a substantial increase in the degree of 1,9-migration of hydrogen.

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Literature cited

  1. O. G. Safiev, U. B. Imashev, and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim.,1979, 2499.

  2. R. Kh. Freidlina and A. B. Terent'ev, Acc. Chem. Res.,10, 9 (1977).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    O. G. Safiev, U. B. Imashev & A. B. Tarent'ev

Authors
  1. O. G. Safiev
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  2. U. B. Imashev
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  3. A. B. Tarent'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1590–1594, July, 1980.

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Safiev, O.G., Imashev, U.B. & Tarent'ev, A.B. 1,5- and 1,9-migration of hydrogen during telomerization of propylene with dimethyl acetal. Russ Chem Bull 29, 1134–1137 (1980). https://doi.org/10.1007/BF00949169

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  • DOI: https://doi.org/10.1007/BF00949169

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