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Reaction of vinyl chloride with bromoform and related compounds in the presence of coordination initiators based on Fe(CO)5

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The telomerization of vinyl chloride (VC) with bromoform, with initiation by coordination initiators based on Fe(CO)5, proceeds with a greater conversion of the telogen and an increased yield of lower telomers when compared with initiation by benzoyl peroxide. Together with the CHBr2 (CH2CHCl)nBr (n=1−3) telomers, a small amount of 1,3-dibromo-1,3-dichloropropane is formed.

  2. 2.

    Under the reaction conditions, the CHBr2CH2CHClBr telomer is capable of reacting with VC, with cleavage of the C-Br bonds of both the CHBr2 and CHClBr groups.

  3. 3.

    We were able to add 1,1,3-tribromopropane and 1,3-dibromo-1-chloropropane to VC by initiation with Fe(CO)5 + DMF.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    T. T. Vasil'eva, G. A. Trapeznikova, V. I. Dostovalova, B. V. Nelyubin & R. Kh. Freidlina

Authors
  1. T. T. Vasil'eva
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  2. G. A. Trapeznikova
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  3. V. I. Dostovalova
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  4. B. V. Nelyubin
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  5. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1584–1590, July, 1980.

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Vasil'eva, T.T., Trapeznikova, G.A., Dostovalova, V.I. et al. Reaction of vinyl chloride with bromoform and related compounds in the presence of coordination initiators based on Fe(CO)5 . Russ Chem Bull 29, 1128–1133 (1980). https://doi.org/10.1007/BF00949168

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  • DOI: https://doi.org/10.1007/BF00949168

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