Oligomerization of ethylene on Pd-aluminosilicate catalysts under pressure
- 23 Downloads
At 100°, with increase in the pressure from 5 to 20 atm the degree of ethylene conversion on impregnated Pd-aluminosilicate and Pd-CaNaX catalysts passed through a maximum at 10–15 atm and was 15–20%.
Under pressure the impregnated Pd-aluminosilicate catalyst exhibits a high selectivity as regards ethylene dimerization. The yield of butenes when based on reacted ethylene reaches 93.5‰
KeywordsEthylene Oligomerization Butene High Selectivity Ethylene Conversion
Unable to display preview. Download preview PDF.
- 1.U. S. Patent 3,758,626 (1973); Ref. Zh. Khim., 16P142P (1974).Google Scholar
- 2.A. L. Lapidus, M. I. Magan'ya, and V. V. Mal'tsev, Neftekhimiya,18, 376 (1978).Google Scholar
- 3.A. L. Lapidus, V. V. Mal'tsev, M. I. Maganya, V. I. Garanin, and Kh. M. Minachev, Proceedings of the Symposium on Zeolites (Hungary); Acta Phys. Chem.,24, 195 (1978).Google Scholar
- 4.A. L. Lapidus, Kh. M. Minachev, V. V. Mal'tsev, V. I. Garanin, and P. I. Slyunyaev, Neftekhimiya,18, 212 (1978).Google Scholar