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Orientation of phenyl group attached to phosphorus atom in 5-phenyl-1,3-di-R-1,3,5-diazaphosphorinanes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The phenyl group in 5-phenyl-1, 3-di-R-1, 3,5-diazaphosphorinanes exists preferentially in an equatorial orientation.

  2. 2.

    An analogy is observed in the change in the conformational free energy of the substituent attached to the carbon and phosphorus atoms when the ring CH2 groups are substituted by oxygen or nitrogen atoms.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, O. A. Erastov, G. N. Nikonov, T. A. Zyablikova, R. P. Arshinova & R. A. Kadyrov

Authors
  1. B. A. Arbuzov
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  2. O. A. Erastov
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  3. G. N. Nikonov
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  4. T. A. Zyablikova
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  5. R. P. Arshinova
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  6. R. A. Kadyrov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1571–1574, July, 1980.

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Arbuzov, B.A., Erastov, O.A., Nikonov, G.N. et al. Orientation of phenyl group attached to phosphorus atom in 5-phenyl-1,3-di-R-1,3,5-diazaphosphorinanes. Russ Chem Bull 29, 1115–1119 (1980). https://doi.org/10.1007/BF00949165

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  • DOI: https://doi.org/10.1007/BF00949165

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