Skip to main content
SpringerLink
Log in

Organoboron compounds 376. Mass-spectrometric study of derivatives of 1,2-azaborqlidine and 1,2-oxaborolane

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Upon exposure to electron impact the decomposition of the molecular ions of 1,2-azaborolidines with an alkyl group at the boron atom involves mainly the formation of a [M-R]+ ion by the splitting off of an alkyl group and elimination of a R-CH3 group under formation of a [M-(R-CH3)]+ ion.

  2. 3.

    For derivatives of 1,2-oxaborolane the processes of ring destruction are much more distinctly developed than for 1,2-azaborolidines.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. B. M. Zolotarev, O. S. Chizhov, A. S. Bleshinskaya, O. G. Boldyreva, V. A. Dorokhov, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 2226 (1979).

  2. V. A. Dorokhov and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 1804 (1970).

  3. B. M. Mikhailov, V. A. Dorokhov, and N. V. Mostovoi, Izv. Akad. Nauk SSSR, Ser. Khim., 201 (1964).

  4. J. C. Kotz, P. J. van den Zanden, and P. G. Cooks, Chem. Commun., 923 (1970).

  5. G. B. Butler and G. L. Staton, J. Am. Chem. Soc.,86, 518 (1964).

    Google Scholar 

  6. V. A. Dorokhov, O. G. Boldyreva, and B. M. Mikhailov, Zh. Obshch. Khim.,40, 1528 (1970).

    Google Scholar 

  7. B. M. Mikhailov, V. A. Dorokhov, N. V. Mostovoi, and I. P. Yakovlev, Zh. Obshch, Khim., Collection: Problems of Organic Synthesis, 223, 228 (1965).

    Google Scholar 

  8. B. M. Mikhailov, V. A. Dorokhov, N. V. Mostovoi, O. G. Boldyreva, and M. N. Bochkareva, Zh. Obshch. Khim.,40, 1817 (1970).

    Google Scholar 

  9. G. L. Gal'chenko, Nguen Zan' Ni, E. P. Brykina, O. G. Boldyreva, V. A. Dorokhov, and B. M. Mikhailov, Vestn. Mosk. Univ. Ser. Khim.,18, 404 (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences USSR, Moscow

    A. S. Bleshinskaya, B. M. Zolotarev, O. S. Chizhov, V. A. Dorokhov, O. G. Boldyreva & B. M. Mikhailov

Authors
  1. A. S. Bleshinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. M. Zolotarev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. S. Chizhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Dorokhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. G. Boldyreva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. M. Mikhailov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1566–1570, July, 1980.

We thank N. A. Klyuev, who measured the high-resolution mass spectra of some samples.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bleshinskaya, A.S., Zolotarev, B.M., Chizhov, O.S. et al. Organoboron compounds 376. Mass-spectrometric study of derivatives of 1,2-azaborqlidine and 1,2-oxaborolane. Russ Chem Bull 29, 1111–1115 (1980). https://doi.org/10.1007/BF00949164

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00949164

Keywords

Search

Navigation