Conclusions
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1.
The kinetics of the catalytic radical dissociation of tetralin hydroperoxide at polydehydrobutoxychrosoidine with the nitroxyl radical were investigated.
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2.
The catalytic activity of polydehydrobutoxychrysoidine is determined by the coppercontaining centers of the polymer. The radical dissociation of tetralin hydroperoxide at the copper-containing polymer is of first order in the concentration of the hydroperoxide and of the polymer, and its rate increases approximately in proportion to the square of the copper content.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1523–1526, July, 1980.
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Shklyaev, A.A., Amosov, Y.I., Terpugova, M.P. et al. Kinetics of radical dissociation of tetralin hydroperoxide on the copper-containing polymer polydehydrobutoxychrysoidine. Russ Chem Bull 29, 1069–1071 (1980). https://doi.org/10.1007/BF00949155
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DOI: https://doi.org/10.1007/BF00949155