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Mechanism of combustion of mixtures of H2 with O + O2, H2O2, and HNO3

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate constants of the reaction of atomic oxygen with hydrogen at 293–1160°K were determined.

  2. 2.

    The rate constants of the trimolecular reaction of atomic hydrogen with oxygen in argon at room temperature were determined.

  3. 3.

    The mechanism of combustion of hydrogen with atomic and molecular oxygen, hydrogen peroxide, and nitric acid was considered and compared with experimental results; in all three cases, the combustion mechanism was similar, but differed with respect to the initial step.

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Literature cited

  1. V. N. Kondrat'ev and E. E. Nikitin, Kinetics and Mechanism of Gas-Phase Reactions [in Russian], Nauka (1974).

  2. V. Ya. Basevich, S. M. Kogarko, and G. A. Furman, Izv. Akad. Nauk SSSR, Ser. Khim., 7 (1975).

  3. V. N. Kondrat'ev, Rate Constants of Gas-Phase Reactions [in Russian], Nauka (1970).

  4. V. Ya. Basevich and S. M. Kogarko, Izv. Akad. Nauk SSSR, Ser. Khim., 2250 (1978).

  5. V. Ya. Basevich, S. M. Kogarko, and O. Yu. Berezin, Izv. Akad. Nauk SSSR, Ser. Khim., 1986 (1979).

  6. W. Hack, H. G. Wagner, and K. Hoyermann, Ber. Bunsenges. Phys. Chem.,82, 713 (1978).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. Ya. Basevich & S. M. Kogarko

Authors
  1. V. Ya. Basevich
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  2. S. M. Kogarko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1503–1509, July, 1980.

The authors thank M. G. Neigauz for allowing them to use the program and for her help in carrying out the calculations on a computer.

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Basevich, V.Y., Kogarko, S.M. Mechanism of combustion of mixtures of H2 with O + O2, H2O2, and HNO3 . Russ Chem Bull 29, 1050–1056 (1980). https://doi.org/10.1007/BF00949152

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  • DOI: https://doi.org/10.1007/BF00949152

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