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Hydrogenation of piperylene on cationic forms of various zeolites

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The 1-pentene-pentene and cis-2-pentene/trans-2-pentene ratios in the reaction products of the hydrogenation of piperylene on the Ca2+ and La3+ forms of various zeolites are close to the values characteristic of the successive addition of hydrogen ions to unsaturated bonds. As the quantum-chemical calculation of the heats of reaction has shown, a hydride ion is added to the piperylene molecule first.

  2. 2.

    The hydrogenating activity of zeolites is determined by the electron affinity of the metal cation.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. V. Kharlamov, N. G. Kharatishvili, Yu. A. Borisov, P. I. Slyunyaev & Kh. M. Minachev

Authors
  1. V. V. Kharlamov
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  2. N. G. Kharatishvili
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  3. Yu. A. Borisov
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  4. P. I. Slyunyaev
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  5. Kh. M. Minachev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1497–1502, July, 1980.

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Kharlamov, V.V., Kharatishvili, N.G., Borisov, Y.A. et al. Hydrogenation of piperylene on cationic forms of various zeolites. Russ Chem Bull 29, 1044–1049 (1980). https://doi.org/10.1007/BF00949151

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  • DOI: https://doi.org/10.1007/BF00949151

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