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A test of the theory of zone spreading in capillary chromatography and an estimate of the contribution CF the resistance to mass transfer at the gas-liquid boundary

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new procedure for the experimental testing of the theory of capillary gas chromatography is proposed.

  2. 2.

    The difference between experiment and Golay's theory due to resistance to mass transfer at the gas-liquid boundary amounts to 23% of the observed height equivalent to a theoretical plate.

  3. 3.

    Taking the finite thickness of the interphase layer and its special absorption properties into account leads to a quadratic form of the dependence of the interphase resistance on the coefficient of mass transfer.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. V. Garbuzov, A. V. Vasil'ev & R. V. Golovnya

Authors
  1. V. V. Garbuzov
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  2. A. V. Vasil'ev
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  3. R. V. Golovnya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1491–1497, July, 1980.

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Garbuzov, V.V., Vasil'ev, A.V. & Golovnya, R.V. A test of the theory of zone spreading in capillary chromatography and an estimate of the contribution CF the resistance to mass transfer at the gas-liquid boundary. Russ Chem Bull 29, 1039–1044 (1980). https://doi.org/10.1007/BF00949150

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  • DOI: https://doi.org/10.1007/BF00949150

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