Steady-flow investigation of the kinetics of the reaction between V02+ and phosphorus-molybdenum-vanadium heteropoly anions

  • Yu. V. Burov
  • I. V. Kozhevnikov
  • K. I. Matveev
  • V. D. Belyaev
Inorganic Chemistry
  • 33 Downloads

Conclusions

  1. 1.

    It is found that the reaction of VO2+ with phosphorus-molybdenum-vanadium heteropoly anions (HPAN-n, n=0-6) at pH 2.2–3.0 obeys the kinetic equation v=k' [HPAN-n] [VO2+]/ [H+] α , whereαa=1.5 for HPAN-0 and 1.8 for HPAN-1, and that it includes the formation of an intraspherical intermediate complex [(HPAN-n), VO2+].

     
  2. 2.

    The reactivity of HPAN-n varies in the following order: HPAN-0 > HPAN-1 > HPAN-2 < HPAN-3 < HPAN-4 < HPAN-5 < HPAN-6.

     

Keywords

Kinetic Equation Intermediate Complex Heteropoly Anion 

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • Yu. V. Burov
    • 1
  • I. V. Kozhevnikov
    • 1
  • K. I. Matveev
    • 1
  • V. D. Belyaev
    • 1
  1. 1.Institute of CatalysisSiberian Branch of the Academy of Sciences of the USSRNovosibirsk

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