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Kinetics and mechanism of thermal decomposition of hydroxylammonium perchlorate and its complex with hydroxylamine

  • Yu. I. Rubtsov
  • E. S. Rumyantsev
  • L. P. Andrienko
  • V. A. Rafeev
  • G. N. Lyubimova
  • G. B. Manelis
Inorganic Chemistry

Conclusions

  1. 1.

    In its initial stages, the decomposition of hydroxylammonium perchlorate involves dissociation of the salt followed by decomposition of a complex of hydroxylamine with hydroxylammonium perchlorate. At elevated temperatures the reaction involving hydroxylamine molecules not bound into complexes plays an increasing part.

     
  2. 2.

    As hydroxylammonium perchlorate decomposes, the leading stage changes. The crucial reaction becomes oxidation of NH3OH+ by perchloric acid, leading to autocatalysis of the process.

     

Keywords

Oxidation Elevated Temperature Thermal Decomposition Perchlorate Perchloric Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    C. B. Manelis, Yu. I. Rubtsov, and A. V. Raevskii, Fiz. Goren. Vzryva,6, 3 (1970).Google Scholar
  2. 2.
    Yu. I. Rubtsov, in: Proceedings of Third Symposium on Combustion and Explosion [in Russian], Nauka (1971), p. 771.Google Scholar
  3. 3.
    V. A. Koroban, T. I. Smirnova, and B. S. Svetlov, Chemical Physics of Combustion and Explosion Processes: Kinetics of Chemical Reactions [in Russian], OIKhF, Chernogolovka (1977), p. 67; V. A. Rafeev, Yu. I. Rubtsov, and A. I. Kazakov, ibid., p. 63.Google Scholar
  4. 4.
    P. H. Quachia, H. Moc, M. A. Klotz, and A. I. Dimilo, Prod. Res. Development,8, 197 (1969).Google Scholar
  5. 5.
    H. F. Cordes and S. R. Smith, J. Inorg. Nucl. Chem.,32, 1135 (1970).Google Scholar
  6. 6.
    O. S. Galyuk, Yu. I. Rubtsov, G. F. Malinovskaya, and G. B. Manelis, Zh. Fiz. Khim.,39, 2319 (1965).Google Scholar
  7. 7.
    A. E. Harvey, M. T. Edmison, E. D. Jones, R. A. Senbert, and K. A. Catto, J. Am. Chem. Soc.,76, 3270 (1954).Google Scholar
  8. 8.
    Paul Pascal, Nouveau Traité de Chimie Minerale, Vol. 10, Masson, Paris (1956), p. 275.Google Scholar
  9. 9.
    Yu. I. Rubtsov, G. B. Manelis, Z. I. Grigorovich, and V. Ya. Rosolovskii, Zh. Fiz. Khim.,48, 1399 (1974).Google Scholar
  10. 10.
    Thermal Constants of Substances [in Russian], Izd. Akad. Nauk SSSR, No. I (1965); No. III (1968).Google Scholar
  11. 11.
    J. B. Levy, J. Phys. Chem.,66, 1092 (1962).Google Scholar

Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • Yu. I. Rubtsov
    • 1
  • E. S. Rumyantsev
    • 1
  • L. P. Andrienko
    • 1
  • V. A. Rafeev
    • 1
  • G. N. Lyubimova
    • 1
  • G. B. Manelis
    • 1
  1. 1.Division of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

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