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Use of the x-ray emission spectroscopy method to study the character of the reaction of titanium disulfide with inserted amines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In TiS2-amine insertion compounds the nitrogen atom is coordinated directly with the titanium atom.

  2. 2.

    The presence of water accelerates the insertion of the amine and leads to the coordination of oxygen-containing compounds to the titanium atoms of TiS2.

  3. 3.

    The TiS2-amine insertion compounds are easily oxidized by atmospheric oxygen at ∼20°C to give TiO2 and S8.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. V. Kozinkin, A. T. Shuvaev, A. S. Golub', Yu. N. Novikov & M. E. Vol'pin

  2. Institute of Physics, Rostov State University, USSR

    A. V. Kozinkin, A. T. Shuvaev, A. S. Golub', Yu. N. Novikov & M. E. Vol'pin

Authors
  1. A. V. Kozinkin
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  2. A. T. Shuvaev
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  3. A. S. Golub'
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  4. Yu. N. Novikov
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  5. M. E. Vol'pin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1429–1431, June, 1984.

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Kozinkin, A.V., Shuvaev, A.T., Golub', A.S. et al. Use of the x-ray emission spectroscopy method to study the character of the reaction of titanium disulfide with inserted amines. Russ Chem Bull 33, 1316–1318 (1984). https://doi.org/10.1007/BF00949013

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  • DOI: https://doi.org/10.1007/BF00949013

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