Relative telomerization rate of trimethylvinylsilane with methyl propionate

  • A. B. Terent'ev
  • N. S. Ikonnikov
Brief Communications
  • 15 Downloads

Conclusions

The telomerization of trimethylvinylsilane with methyl propionate is accompanied by a rearrangement of the Me3SiĊHCH2CH(Me)CO2Me radicals and a 1,3-migration of hydrogen.

Keywords

Hydrogen Methyl Propionate Telomerization Methyl Propionate 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 2645 (1983).Google Scholar
  2. 2.
    A. B. Terent'ev, M. A. Churilova, N. S. Ikonnikov, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 439 (1975).Google Scholar
  3. 3.
    N. S. Ikonnikov and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 371 (1975).Google Scholar
  4. 4.
    R. Kh. Freidlina, A. B. Terent'ev, N. S. Ikonnikov, and M. A. Churilova, Dokl. Akad. Nauk SSSR,208, 1366 (1973).Google Scholar
  5. 5.
    H. Sakurai, A. Hosomi, and M. Kumada, J. Org. Chem.,34, 1764 (1969).Google Scholar
  6. 6.
    R. A. Benkeser, E. W. Bennet, and R. A. Hichner, J. Am. Chem. Soc.,79, 6253 (1957).Google Scholar
  7. 7.
    L. Goodman, R. M. Silverstein, and C. W. Gouls, J. Org. Chem.,22, 596 (1957).Google Scholar
  8. 8.
    L. Sommer, in: Stereochemistry and Reaction Mechanism of Organosilicon Compounds [Russian translation], Mir, Moscow (1966), pp. 18–22.Google Scholar
  9. 9.
    F. Mayo, J. Am. Chem. Soc.,70, 3689 (1948).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • A. B. Terent'ev
    • 1
  • N. S. Ikonnikov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations