Conclusions
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1.
The rate constants for the oxidation of the aqua and chloro complexes of Co(II), Fe(II), and Mn(II) by the Cl2 −-ion-radical in aqueous solutions were measured by the pulse radiolysis method.
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2.
A substantial increase was observed in the oxidation rate with increase in the number of chloride ions in the inner coordination sphere of the complex was observed.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1419–1421, June, 1984.
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Gogolev, A.V., Makarov, I.E. & Pikaev, A.K. Study of reactivity of Cl2 −-toward aqua and chloro complexes of Co(II), Fe(II), and Mn(II) in aqueous solutions by pulse radiolysis method. Russ Chem Bull 33, 1307–1309 (1984). https://doi.org/10.1007/BF00949008
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DOI: https://doi.org/10.1007/BF00949008