Photoreduction of 2,6-di-tert-butyl-1,4-benzoquinone by aliphatic tertiary amines

  • M. V. Serdobov
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Conclusions

The photoreduction of 2,6-di-tert-butyl-1,4-benzoquinone by tertiary aliphatic amines proceeds in donor-acceptor complexes of 1∶1 and 1∶2 composition. The radical pairs that are obtained by the photolysis of these systems in glassy solutions at 77°K are formed by neutral radicals.

Keywords

Benzoquinone Photolysis Radical Pair Tertiary Amine Aliphatic Amine 

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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • M. V. Serdobov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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