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Conclusions

li1.

  1. 2.

    Oxidation of N-(β-hydroxyethyl)-N-nitrosulfonamide by chromic anhydride leads to the formation of an α-carboxyl derivative of N-nitrosulfonamide.

  2. 3.

    By reaction with alcohols, α-keto derivatives of N-nitrosulfonamides convert into N-(α-keto-α-alkoxyalkyl)sulfonamides.

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Literature cited

  1. A. A. Onishchenko, O. S. Reshetova, V. P. Gorelik, O. A. Luk'yanov, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1166 (1976).

  2. Houben-Weyl, Methoden der Organischen Chemie, Vol. 2, Stuttgart (1963), p. 448.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1349–1351, June, 1984.

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Luk'yanov, O.A., Onishchenko, A.A., Salamonov, Y.B. et al. α-keto derivatives of N-nitramides and N-nitramines. Russ Chem Bull 33, 1239–1242 (1984). https://doi.org/10.1007/BF00948995

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  • DOI: https://doi.org/10.1007/BF00948995

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