Conclusions
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1.
The molecular and crystal structure was found for bi (1-α-naphthyl-1-silacyclobutyl), the first monosilacyclobutane derivative containing an Si-Si bond. The silacyclobutane fragment has almost planar conformation with slight differences in the C-C bond lengths.
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2.
A comparison of the geometric configuration of silacyclobutanes indicates that their Si...β-C distances are characteristically constant. This invariance is achieved by variations in the ring flexure angle ϕ and in the endocyclic CCC bond angle, which are related by a linear equation.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1314–1319, June, 1984.
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D'yachenko, O.A., Sokolova, Y.A., Atovmyan, L.O. et al. An x-ray diffraction structural analysis of 1,1-bi(1-α-naphthyl-1-silacyclobutyl), the first monosilacyclobutane derivative with an Si-Si bond. Russ Chem Bull 33, 1207–1212 (1984). https://doi.org/10.1007/BF00948989
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DOI: https://doi.org/10.1007/BF00948989