Skip to main content
SpringerLink
Log in

Fragmentation of the adducts of perfluoromethyl vinyl ether with halo- and nitronium fluorosulfates under electron impact

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The mass spectra of CF3OCF(OSO2F)CF2X (X=halogen, NO2) and some model compounds have been studied. It has been established that the molecular cation-radicals of these compounds are not stable. The main breakdown processes of the even-electron fragment ions occur with migration of halogen atoms or fluorosulfate groups to neighboring carbon atoms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, Tzhe Ngem Nguen, D. V. Zagorevskii, and V. I. Bakhmutov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 7 (1984).

  2. V. V. Takhistov, Practical Mass Spectrometry of Organic Compounds [in Russian], Izd. Leningr. Un-ta, Leningrad, (1977), p. 120.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. V. Fokin, D. V. Zagorevskii, Yu. S. Nekrasov & A. I. Rapkin

Authors
  1. A. V. Fokin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. V. Zagorevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. S. Nekrasov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Rapkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimiya, No. 6, pp. 1311–1314, June, 1984.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fokin, A.V., Zagorevskii, D.V., Nekrasov, Y.S. et al. Fragmentation of the adducts of perfluoromethyl vinyl ether with halo- and nitronium fluorosulfates under electron impact. Russ Chem Bull 33, 1204–1206 (1984). https://doi.org/10.1007/BF00948988

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00948988

Keywords

Search

Navigation