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ESR determination of the rate constant for the addition of CpW(CO)3 to spin traps

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Conclusions

The reaction of [CpW(CO)3]2 with PhCH2Cl and the decomposition of CpW(CO)3Me were studied by ESR spectroscopy using 2,4,6-tri-tert-butyinitrobenzene (BNB) and α-phenyl-N-tert-butylnitrone (PNB) as spin traps. The rate constants for the addition of CpW(CO)3 radicals to the spin traps at ∼ 20°C were determined by identification of the intermediate radicals in these reactions: k BNBad =6.7·105-7.0·105 and k PNBad =5.8·104-6.1·104 liters/mole · sec.

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Literature cited

  1. R. Kh. Freidlina, I. I. Kandror, and R. G. Gasanov, Usp. Khim.,47, 508 (1978).

    Google Scholar 

  2. V. E. Zubarev, V. N. Belevskii, and L. T. Bugaenko, Usp. Khim., 48, 1361 (1979).

    Google Scholar 

  3. M. J. Perkins, in: Advances in Physical Organic Chemistry, Vol.17, Academic Press (1980), p. 1.

  4. E. Ts. Chukovskaya, R. G. Gasanov, I. I. Kandror, and R. Kh. Freidlina, Zn. Vses. Khim. Obshch. im. D. I. Mandeleeva,24, 161 (1979).

    Google Scholar 

  5. R. G. Gasanov and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,235, 1309 (1977).

    Google Scholar 

  6. R. G. Gasanov and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,254, 113 (1980).

    Google Scholar 

  7. R. G. Gasanov and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Knim., 1244 (1981).

  8. R. G. Gasanov, L. V. Ivanova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1045 (1983).

  9. S. Terabe and R. Konaka, J. Chem. Soc., Perkin Trans.2, 369 (1973).

    Google Scholar 

  10. R. M. Laine and P. C. Ford, Inorg. Cnem.,16, 388 (1977).

    Google Scholar 

  11. B. L. Tumanskii, A. N. Degtyarev, N. N. Bubnov, S. P. Solodovnikov, V. I. Bregadze, N. N. Godovikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 2627 (1980).

  12. R. G. Gasanov, L. V. Ivanova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1011 (1982).

  13. E. T. Denisov, Rate Constants of Homolytic Liquid-Phase Reactions [in Russian], Izd. Nauka, Moscow (1971), p. 262.

    Google Scholar 

  14. Y. Maeda and K. U. Ingold, J. Am. Chem. Soc.,101, 4975 (1979).

    Google Scholar 

  15. A. N. Nesmeyanov, T. V. Nikitina, and O. V. Nogina, Methods in Heteroorganic Chemistry, Copper, Scandium, Titanium, Vanadium, Chromium, Manganese Subgroup. Lanthanides and Actinides [in Russian], Book 2, Nauka, Moscow (1974).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Chemistry, Academy of Sciences of the USSR, Moscow

    R. G. Gasanov & R. Kh. Freidlina

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  1. R. G. Gasanov
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  2. R. Kh. Freidlina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2631–2633, November, 1984.

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Gasanov, R.G., Freidlina, R.K. ESR determination of the rate constant for the addition of CpW(CO)3 to spin traps. Russ Chem Bull 33, 2409–2411 (1984). https://doi.org/10.1007/BF00948869

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  • DOI: https://doi.org/10.1007/BF00948869

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