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Synthesis of ω-haloalkanoic acids by the catalytic decomposition of cycloalkane hydroperoxides by copper ions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The action of catalytic amounts of copper ions in the presence of MX salts (M=K and Na, X=Cl, Br, I, SCN) leads to the decomposition of the hydroperoxides of C5-C7 cycloalkanones with the formation of ω-chloro-,ω-bromo-, ω-iodo-, and ω-thiocyanoalkanoic acids.

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Literature cited

  1. E. G. E. Hawkins, J. Chem. Soc., 3463 (1955).

  2. F. Minisci, Gazz. Chim. Ital.,89, 1910 (1959).

    Google Scholar 

  3. F. Minisci, Gazz. Chim. Ital.,89, 2428 (1959).

    Google Scholar 

  4. H. E. De La Mare, J. K. Kochi, and F. F. Rust, J. Am. Chem. Soc.,85, 1437 (1963).

    Google Scholar 

  5. N. A. Milas, S. A. Harries, and P. S. Panagiotocos, J. Am. Chem. Soc., 2430 (1939).

  6. Yu. V. Il'in, V. A. Plakhotnik, V. G. Giukhovtsev, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 2243 (1982).

  7. K. J. McCullough, A. R. Morgan, D. C. Nonhebel, P. L. Pauson, and G. J. White, J. Chem. Res. (S), 34 (1980).

  8. Weygand-Hilgetag, Experimental Methods in Organic Chemistry [Russian translation], Khimiya, Moscow (1968), p. 548.

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2628–2630, November, 1984.

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Nikishin, G.I., Aleksandrov, A.V., Ignatenko, A.V. et al. Synthesis of ω-haloalkanoic acids by the catalytic decomposition of cycloalkane hydroperoxides by copper ions. Russ Chem Bull 33, 2407–2409 (1984). https://doi.org/10.1007/BF00948868

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  • DOI: https://doi.org/10.1007/BF00948868

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