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Chemical transformations of 1,3,3,5-tetrachlorononane initiated by Fe(CO)5, Me(CO)6 and Mn2(CO)10 systems

  • N. A. Rybakova
  • L. N. Kiseleva
  • R. Kh. Freidlina
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Conclusions

A study was carried out on the competitive reactions of CICH2CH2ĊClCH2CHClC4H9 (A) generated from 1,3,3,5-tetrachlorononane by the action of Fe(CO)5, Mo(CO)6, and Mn2(CO)10 systems. The Mn2(CO)10 systems were most efficient for obtaining the reaction of (A) radicals with hydrogen donors, while the Fe(CO)5 systems were most efficient for obtaining rearrangements of (A) radicals with 1,5- and 1,6-hydrogen migration and subsequent reaction with a chlorine donor and Mo(CO)6 and Mn2(CO)10 systems were most efficient in effecting disproportionation of (A) radicals.

Keywords

Hydrogen Migration Chlorine Disproportionation Chemical Transformation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    L. N. Kiseleva, N. A. Rybakova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2408 (1983).Google Scholar
  2. 2.
    N. A. Rybakova, L. N. Kiseleva, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 597 (1983).Google Scholar
  3. 3.
    R. G. Gasanov and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,239, 94 (1978).Google Scholar
  4. 4.
    N. A. Kuz'mina, N. P. Zhiryukhina, E. Ts. Chukovskaya, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2090 (1981).Google Scholar
  5. 5.
    E. Ts. Chukovskaya (E. C. Chukovskaya), V. I. Dostovalova, T. T. Vasil'eva, and R. Kh. Freidlina, Org. Magn. Reson.,8, 229 (1976).Google Scholar
  6. 6.
    N. A. Rybakova, E. Ts. Chukovskaya, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2618 (1979).Google Scholar

Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • N. A. Rybakova
    • 1
  • L. N. Kiseleva
    • 1
  • R. Kh. Freidlina
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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