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Pressure dependence of the rate constants of liquid-phase hydrogen atom radical abstraction reactions and its use for determining the steric components of the activation volume

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An equation was obtained which describes the effect of pressure on the rate constants of liquid-phase hydrogen abstraction reactions.

  2. 2.

    The contribution of the steric component to the activation volume was found in the abstraction of hydrogen atoms from sterically hindered phenols by diphenylpicrylhydrazyl.

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Authors and Affiliations

  1. N.D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    E. M. Vasil'vitskaya, B. S. Él'yanov & V. M. Zhulin

Authors
  1. E. M. Vasil'vitskaya
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  2. B. S. Él'yanov
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  3. V. M. Zhulin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2607–2610, November, 1984.

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Vasil'vitskaya, E.M., Él'yanov, B.S. & Zhulin, V.M. Pressure dependence of the rate constants of liquid-phase hydrogen atom radical abstraction reactions and its use for determining the steric components of the activation volume. Russ Chem Bull 33, 2388–2390 (1984). https://doi.org/10.1007/BF00948860

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  • DOI: https://doi.org/10.1007/BF00948860

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