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Oxidation of palladium(II) chelates with 1,2-hydroxylaminooximes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When oxidants act on palladium(II) chelates with 1,2-hydroxylaminooximes, oxidative hydrogenation occurs via the N=H bond of the coordinated ligands.

  2. 2.

    It has been shown by EPR that an intermediate in the oxidation is a palladium(II) complex that contains a nitroxyl radical.

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Literature cited

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    S. V. Larionov, L. A. Kosareva & E. G. Boguslavskii

  2. Novosibirsk State University, USSR

    S. V. Larionov, L. A. Kosareva & E. G. Boguslavskii

Authors
  1. S. V. Larionov
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  2. L. A. Kosareva
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  3. E. G. Boguslavskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2592–2596, November, 1984.

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Larionov, S.V., Kosareva, L.A. & Boguslavskii, E.G. Oxidation of palladium(II) chelates with 1,2-hydroxylaminooximes. Russ Chem Bull 33, 2374–2377 (1984). https://doi.org/10.1007/BF00948856

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  • DOI: https://doi.org/10.1007/BF00948856

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