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Reactions of organometallic compounds, catalyzed by transition metal complexes. 8. Carbonylation of arylmercury compounds in the presence of palladium and rhodium

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It has been found that in the presence of iodide ion the carbonylation of arylmereury compounds R2Hg and RHgX (R=p-ClC6H4, Ph, p-MeC6H4, p-MeOC6H4, p-Me2NC6H4, p-H2NC6H4, o-HOC6H4, 2-thienyl; X=Cl, Br, OAc), catalyzed by palladium and rhodium complexes, proceeds under very mild conditions (1 atm CO, 20°C) to give high yields of symmetrical diaryl ketones.

  2. 2.

    The effects of type of solvent and catalyst, and the type and amount of halide ion have been examined, and the optimum conditions for carbonylation have been found.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. A. Bumagin, I. O. Kalinovskii & I. P. Beletskaya

  2. L. Ya. Karpov Physicochemical Institute, Moscow

    N. A. Bumagin, I. O. Kalinovskii & I. P. Beletskaya

Authors
  1. N. A. Bumagin
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  2. I. O. Kalinovskii
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  3. I. P. Beletskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2586–2591, November, 1984.

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Bumagin, N.A., Kalinovskii, I.O. & Beletskaya, I.P. Reactions of organometallic compounds, catalyzed by transition metal complexes. 8. Carbonylation of arylmercury compounds in the presence of palladium and rhodium. Russ Chem Bull 33, 2368–2373 (1984). https://doi.org/10.1007/BF00948855

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  • DOI: https://doi.org/10.1007/BF00948855

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