Skip to main content
SpringerLink
Log in

Reactions of organometallic compounds, catalyzed by transition metal complexes. 7. Oxidative demercuration of arylmercury in the presence of complexes of palladium and rhodium

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The effects of adding halide ion, type of solvent and catalyst on the oxidative demercuration of arylmercury compounds in the presence of palladium and platinum complexes have been studied.

  2. 2.

    In the presence of halide ion, arylmercury compounds Ar2Hg and ArHgX (Ar=p-ClC6H4, Ph, P-MeC6-H4, p-MeOC6H4, p-Me2NC6H4, p-H2NC6H4, 2-thienyl; X=Cl, OAc) undergo oxidative demercuration catalyzed by palladium and rhodium complexes, under very mild conditions (20°C), to give symmetrical diaryls in high yields.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. A. Bumagin, I. O. Kalinovskii, and I. P. Beletskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1619 (1983).

  2. K. Takagi, N. Hayama, T. Okamoto, Y. Sakakibara, and S. Oka, Bull. Chem. Soc. Jpn.,50, 2741 (1977).

    Google Scholar 

  3. R. C. Larock and J. C. Bernhardt, J. Org. Chem.,42, 1680 (1977).

    Google Scholar 

  4. S. Winstein, L. V. Savedoff, S. Smith, I. D. R. Stevens, and G. S. Gall, Tetrahedron Lett., 24 (1960).

  5. V. V. Bashilov, V. I. Sokolov, and O. A. Reutov, Dokl. Akad. Nauk SSSR,228, 603 (1976).

    Google Scholar 

  6. V. I. Sokolov, V. V. Bashilov, and O. A. Reutov, J. Organomet. Chem.,111, C13 (1976).

    Google Scholar 

  7. O. A. Reutov, I. P. Beletskaya, and V. I. Sokolov, Reaction Mechanisms of Organometallic Compounds [in Russian], Khimiya, Moscow (1972), p. 317.

    Google Scholar 

  8. D. D. Perrin, W. L. F. Armarego, and D. R. Perrin, Purification of Laboratory Chemicals, Pergamon Press, Oxford (1966).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. A. Bumagin, I. O. Kalinovskii & I. P. Beletskaya

  2. L. Ya. Karpov Physicochemical Institute, Moscow

    N. A. Bumagin, I. O. Kalinovskii & I. P. Beletskaya

Authors
  1. N. A. Bumagin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. O. Kalinovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. P. Beletskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2580–2585, November, 1984.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bumagin, N.A., Kalinovskii, I.O. & Beletskaya, I.P. Reactions of organometallic compounds, catalyzed by transition metal complexes. 7. Oxidative demercuration of arylmercury in the presence of complexes of palladium and rhodium. Russ Chem Bull 33, 2364–2368 (1984). https://doi.org/10.1007/BF00948854

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00948854

Keywords

Search

Navigation