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Halogen derivatives of nitroxyl radicals of imidazoline

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    On halogenation of derivatives of 3-imidazoline or N-formylimidazoline mono-, di-, and trihaloalkyl derivatives of nitroxyl radicals of 3-imidazoline were obtained.

  2. 2.

    Participation of the radical center in reactions of the halomethyl derivatives of 3-imldazoline with nucleophilic reagents was detected and a difference was found in the direction of the reaction of chloro and bromo derivatives with bases.

  3. 3.

    A reductive dehalogenation reaction was discovered which led to the formation of dihalomethyl derivatives of 3-imidazoline from trihalomethyl derivatives and took place under the action of an aqueous alcohol solution of sodium hypobromite or amide in liquid ammonia.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    V. A. Reznikov & L. B. Volodarskii

Authors
  1. V. A. Reznikov
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  2. L. B. Volodarskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2565–2570, November, 1984.

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Reznikov, V.A., Volodarskii, L.B. Halogen derivatives of nitroxyl radicals of imidazoline. Russ Chem Bull 33, 2349–2354 (1984). https://doi.org/10.1007/BF00948852

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  • DOI: https://doi.org/10.1007/BF00948852

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