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1,3-disubstituted 1,1,5,5-tetranitropentane-3-nitronic acids

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of salts of 1,1,1,3,5,5,5-hepta- and 1,5-difluoro-1,1,3,5,5-pentanitropentane with trifluoroacetic acid yields 1,1,1,5,5,5-hexa- and 1,5-difluoro-1,1,5,5-tetranitropentane-3-nitronic acids.

  2. 2.

    The chemical shifts of the OH protons of 1,5-substituted 1,1,5,5-tetranitro-3-nitronic acids are similar to those of unsubstituted carboxylic acids.

  3. 3.

    Fluorination, chlorination, and bromination of 1,1,1,5,5,5-hexa- and 1,5-difluoro-1,1,5,5-tetranitropentane-3-nitronic acids yields the respective 3-halo derivatives.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    L. T. Eremenko, G. V. Oreshko, M. A. Fadeev, G. V. Lagodzinskaya & V. I. Shestov

Authors
  1. L. T. Eremenko
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  2. G. V. Oreshko
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  3. M. A. Fadeev
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  4. G. V. Lagodzinskaya
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  5. V. I. Shestov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2555–2557, November, 1984.

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Eremenko, L.T., Oreshko, G.V., Fadeev, M.A. et al. 1,3-disubstituted 1,1,5,5-tetranitropentane-3-nitronic acids. Russ Chem Bull 33, 2339–2341 (1984). https://doi.org/10.1007/BF00948849

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  • DOI: https://doi.org/10.1007/BF00948849

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