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Spectral studies of fluoropolynitroalkylnitramines

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The frequency of the vibrations of the CF bond in polyfluoropolynitroalkylnitramines was identified and calculated; it exhibits a narrow range of changes for the different compounds and decreases on substitution of the 3,3,3-fluorodinitropropyl radical by the 2,2,2-fluorodinitroethyl radical.

  2. 2.

    The frequencies of the asymmetric vibrations of the nitramine group decreased on substitution of the trinitromethyl group by the fluorodinitromethyl group were also not dependent on the number of nitramine groups.

  3. 3.

    Broadening or splitting of the absorption band corresponding to the asymmetric vibrations of the nitro group takes place due to the nonequivalence of the nitro groups.

  4. 4.

    The number of bands corresponding to the vibrations of an ether group was decreased due to the shielding effect of the nitramine group.

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Literature cited

  1. L. T. Eremenko, N. G. Zhitomirskaya, and D. A. Netherenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2593 (1973).

  2. L. T. Eremenko, R. G. Gafurov, D. A. Netherenko, A. G. Korepin, and N. S. Natsibullina, Izv. Akad. Nauk SSSR, Ser. Khim., 2562 (1969).

  3. L. T. Eremenko, R. G. Gafurov, and A. G. Korepin, Izv. Akad. Nauk SSSR, Ser. Khim., 445, (1970).

  4. R. G. Gafurov, A. G. Korepin, and L. T. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1876 (1972).

  5. R. G. Gafurov, A. G. Korepin, and L. T. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2825 (1973).

  6. L. T. Eremenko, N. G. Zhitomirskaya, and G. V. Oreshko, Izv. Akad. Nauk SSSR, Ser. Khim., 2680 (1969).

  7. L. T. Eremenko, N. G. Zhitomirskaya, and G. V. Oreshko, Izv. Akad. Nauk SSSR, Ser. Khim., 2674 (1969).

  8. L. Bellamy, The Infrared Spectra of Complex Molecules, Halsted Press (1975).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    L. T. Eremenko & N. G. Zhitomirskaya

Authors
  1. L. T. Eremenko
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  2. N. G. Zhitomirskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2525–2528, November, 1984.

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Eremenko, L.T., Zhitomirskaya, N.G. Spectral studies of fluoropolynitroalkylnitramines. Russ Chem Bull 33, 2313–2315 (1984). https://doi.org/10.1007/BF00948844

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  • DOI: https://doi.org/10.1007/BF00948844

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