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Enantiomeric analysis of amino acid derivatives on a glass capillary column

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Highly reproducible glass capillary columns are obtained by a static high pressure method with a t-butylamido-N-docosanoyl-L-valine chiral phase, having a high selectivity and effectiveness in enantiomeric separations of derivatives of racemic amino acids, and stability at temperatures up to 175°C.

  2. 2.

    By using short capillary columns (as short as 5 m) enantiomeric separations of high-boiling amino acid derivatives were carried out: esters of D,L-N-acetylphenylalanine, D,L-N-Benzoylvaline, and D,L-N-TFA-tryptophane.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. R. Lyubeznova, K. V. Belyaeva, V. A. Ferapontov, E. I. Karpeiskaya & E. I. Klabunovskii

Authors
  1. M. R. Lyubeznova
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  2. K. V. Belyaeva
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  3. V. A. Ferapontov
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  4. E. I. Karpeiskaya
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  5. E. I. Klabunovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2482–2486, November 1984.

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Lyubeznova, M.R., Belyaeva, K.V., Ferapontov, V.A. et al. Enantiomeric analysis of amino acid derivatives on a glass capillary column. Russ Chem Bull 33, 2271–2275 (1984). https://doi.org/10.1007/BF00948836

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  • DOI: https://doi.org/10.1007/BF00948836

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