Conclusions
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1.
Recombination of carboxy radicals in a primary “cage” takes place in the homolytic decomposition of dicyclohexylperoxydicarbonate (CPC).
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2.
Chain breaking occurs in the kinetic region during decomposition of CPC.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2473–2476, November, 1984.
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Zhulin, V.M., Lipovich, T.V. & Antonovskii, V.L. Effect of high pressure on the rate of homolytic decomposition of dicyclohexylperoxydicarbonate in the liquid phase. Russ Chem Bull 33, 2262–2264 (1984). https://doi.org/10.1007/BF00948834
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DOI: https://doi.org/10.1007/BF00948834