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Redox reactions in micellar systems Communication 1. Reduction of methyl viologen by ketyl radical

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the reaction of benzophenone-photosensitized reduction of methyl viologen in octyl alcohol and in a mixture of isopropyl alcohol and water.

  2. 2.

    For a complete explanation of the relationships observed in the occurrence of the reaction, consideration must be given to the stage of benzophenone triplet quenching by methyl viologen.

  3. 3.

    Extraction of methyl viologen by inverse micelles of sodium dodecylsulfate leads to an increase in the rate of photoreduction of methyl viologen, owing to a reduction of the rate of benzophenone triplet quenching.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2456–2462, November, 1984.

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Burbo, E.M., Gasanova, L.V. & Dzhabiev, T.S. Redox reactions in micellar systems Communication 1. Reduction of methyl viologen by ketyl radical. Russ Chem Bull 33, 2246–2251 (1984). https://doi.org/10.1007/BF00948831

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  • DOI: https://doi.org/10.1007/BF00948831

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