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Enantioselective hydrogenation of ethyl acetoacetate on copper-nickel catalysts and effect of catalyst preparation conditions

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Enantioselective hydrogenation of ethyl acetoacetate was carried out for the first time on unsupported 1∶1 Cu-Ni catalysts obtained by precipitation. The highest optical yield (50%) was obtained with a catalyst obtained by reduction of oxides at 250°C in a 1∶10 H2∶N2 atmosphere.

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Literature cited

  1. E. I. Klabunovskii, A. A. Vedenyapin, G. Kh. Areshidze, and A. K. Ivanov, 12V. Akad. Nauk SSSR, Ser. Khim., 2542 (1976).

  2. G. Kh. Areshidze, Dissertation, Moscow (1971).

  3. Yu. V. Vlasenko, E. I. Klabunovskii, A. A. Vedenyapin, L. N. Brezzhunova, and I. A. Rubtsov, Izv. Akad. Nauk SSSR, Ser. Khim., 680 (1977).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Chernysheva, N. D. Zubareva & E. I. Klabunovskii

Authors
  1. V. A. Chernysheva
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  2. N. D. Zubareva
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  3. E. I. Klabunovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No, 11, pp. 2443–2444, November, 1984.

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Chernysheva, V.A., Zubareva, N.D. & Klabunovskii, E.I. Enantioselective hydrogenation of ethyl acetoacetate on copper-nickel catalysts and effect of catalyst preparation conditions. Russ Chem Bull 33, 2233–2234 (1984). https://doi.org/10.1007/BF00948827

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  • DOI: https://doi.org/10.1007/BF00948827

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