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Structure of O-semiquinolate complexes of tin and titanium trifluorides

  • A. I. Prokof'ev
  • Z. K. Kasymbekova
  • N. N. Bubnov
  • S. P. Solodovnikov
  • M. E. Ignatov
  • E. G. Il'in
  • M. I. Kabachnik
Physical Chemistry
  • 19 Downloads

Conclusions

The interaction of substituted o-benzoquinones with tin and titanium tetrafluorides leads to the formation of the o-semiquinolate complex of the corresponding metal trifluoride. The tin-containing complexes exist in two forms of an octahedral structure differing in the mutual location of the added ligands; the ratio of these forms depends on the nature of the solvent. The titanium-containing complexes are obtained in a single form, owing to the different ligand repulsion energy when the size of the central atom is changed.

Keywords

Titanium Central Atom Mutual Location Single Form Octahedral Structure 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • A. I. Prokof'ev
    • 1
  • Z. K. Kasymbekova
    • 1
  • N. N. Bubnov
    • 1
  • S. P. Solodovnikov
    • 1
  • M. E. Ignatov
    • 1
  • E. G. Il'in
    • 1
  • M. I. Kabachnik
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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