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Vibration spectra and conformation of α,α-dichloromethyl alkyl ethers

  • A. A. Bredikhin
  • V. L. Furer
  • A. M. Salikhova
  • A. N. Vereshchagin
Physical Chemistry
  • 18 Downloads

Conclusions

  1. 1.

    The conformational composition of MeOCHCl2 has been established and the differences between the enthalpies of the conformers in the solutions have been determined by vibrational spectroscopy methods. The data on the parameters of the conformational equilibrium in the gaseous phase were outlined by extrapolation.

     
  2. 2.

    It was shown that in liquid samples of ROCHCl2 (R=Et, i-Pr), the CHCl2 fragment has a γ- and τ-orientation. During crystallization only the gg-isomers that differ in the conformation of the alkyl fragment are retained.

     

Keywords

Spectroscopy Ether Crystallization Enthalpy Gaseous Phase 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • A. A. Bredikhin
    • 1
  • V. L. Furer
    • 1
  • A. M. Salikhova
    • 1
  • A. N. Vereshchagin
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' BranchAcademy of Sciences of the USSRUSSR

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