EPR determination of rate constant of splitting chlorine from CCl4 by telomeric radicals CCl3(CH2CHCl)n· (n=1,2) and their addition to vinyl chloride and nitrosodurene

  • R. G. Gasanov
  • L. V. Ivanova
  • N. A. Grigor'ev
Physical Chemistry
  • 23 Downloads

Conclusions

  1. 1.

    Rate constants of splitting the chlorine atom from CCl4 by the CCl3(CH2CHCl)n· radicals and addition of these radicals to vinyl chloride and nitrosodurene at 40°C were determined by the EPR method.

     
  2. 2.

    It was shown that in the telomerization of vinyl chloride with CCl4, the changes in the individual chain transfer constants are due to changes in the values of both the chain transfer and chain propagation rate constants.

     

Keywords

Chloride Chlorine Vinyl CCl4 Propagation Rate 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    R. G. Gasanov, L. V. Ivanova, and R. Kh. Friedlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1011 (1982).Google Scholar
  2. 2.
    R. G. Gasnov, L. V. Ivanova, N. A. Grigor'ev, A. L. Tumanskaya, and R. Kh. Friedlina, Dokl. Akad. Nauk SSSR,273, 1410 (1983).Google Scholar
  3. 3.
    P. S. Schmid and K. U. Ingold, J. Am. Chem. Soc.,100, 2493 (1978).Google Scholar
  4. 4.
    Y. Maeda and K. U. Ingold, J. Am. Chem. Soc.,101, 4975 (1975).Google Scholar
  5. 5.
    T. A. Onishchenko, Dissertation [in Russian], Moscow (1971).Google Scholar
  6. 6.
    F. K. Velichko, Dissertation [in Russian], Moscow (1957).Google Scholar
  7. 7.
    R. G. Gasanov, L. V. Ivanova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2810 (1979).Google Scholar
  8. 8.
    R. G. Gasanov, L. V. Ivanova, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,255, 1155 (1980).Google Scholar

Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • R. G. Gasanov
    • 1
  • L. V. Ivanova
    • 1
  • N. A. Grigor'ev
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations