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Complex of vanadium(5+) with the dioxygen radical-anion in the catalyzed disproportionation of hydrogen peroxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The intermediate formation of vanadium(5+) peroxo complexes was detected under conditions of the disproportionation of hydrogen peroxide in acetic acid catalyzed by ammonium metavanadate by51V NMR spectroscopy and the complex of vanadium(5+) ions with the dioxygen radical-anion was detected by ESR spectroscopy.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    A. P. Makarov, A. E. Gekhman, V. M. Nekipelov, E. P. Talzi, O. Ya. Polotnyuk, K. I. Zamaraev & I. I. Moiseev

  2. Research Institute for Organic Intermediates and Dyes, Moscow

    A. P. Makarov, A. E. Gekhman, V. M. Nekipelov, E. P. Talzi, O. Ya. Polotnyuk, K. I. Zamaraev & I. I. Moiseev

  3. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Moscow

    A. P. Makarov, A. E. Gekhman, V. M. Nekipelov, E. P. Talzi, O. Ya. Polotnyuk, K. I. Zamaraev & I. I. Moiseev

Authors
  1. A. P. Makarov
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  2. A. E. Gekhman
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  3. V. M. Nekipelov
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  4. E. P. Talzi
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  5. O. Ya. Polotnyuk
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  6. K. I. Zamaraev
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  7. I. I. Moiseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1914–1917, August, 1985.

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Makarov, A.P., Gekhman, A.E., Nekipelov, V.M. et al. Complex of vanadium(5+) with the dioxygen radical-anion in the catalyzed disproportionation of hydrogen peroxide. Russ Chem Bull 34, 1764–1767 (1985). https://doi.org/10.1007/BF00948536

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  • DOI: https://doi.org/10.1007/BF00948536

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