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Reaction of dialkylphosphorous acids with sterically hindered benzoquinonimines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dialkylphosphorous acids in the presence of Et2O·BF3 add to the 1-phenylimine of 3,5-di-tert-butyl-4-benzoquinone at the C=N bond to form dialkyl α-aminoquinolphosphonates.

  2. 2.

    Diethylphosphorous acid reacts with 3,5-di-tert-butyl-1,4-benzoquinone to give O,O-diethyl-3,5-di-tert-butyl-4-hydroxyphenyl phosphate.

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Literature cited

  1. B. A. Arbuzov, N. A. Polezhaeva, and V. S. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 1219 (1960).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    M. G. Pavlichenko, B. E. Ivanov, B. I. Pantukh, V. N. Eliseenkov & F. B. Gershanov

Authors
  1. M. G. Pavlichenko
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  2. B. E. Ivanov
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  3. B. I. Pantukh
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  4. V. N. Eliseenkov
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  5. F. B. Gershanov
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Translated from Izvestlya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1909–1911, August, 1985.

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Pavlichenko, M.G., Ivanov, B.E., Pantukh, B.I. et al. Reaction of dialkylphosphorous acids with sterically hindered benzoquinonimines. Russ Chem Bull 34, 1759–1761 (1985). https://doi.org/10.1007/BF00948534

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  • DOI: https://doi.org/10.1007/BF00948534

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