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Reactions of 1-methyl-1-β-pyridyl-1-silacyclobutane with opening and retention of the silicon-carbon ring

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An anomalously high tendency was found for 1-methyl-1-β-pyridyl-1-silacyclobutane to undergo opening of the silacyclobutane ring by the action of water.

  2. 2.

    The quaternization of 1-methyl-1-β-pyridyl-1-silacyclobutane by methyl iodide at the nitrogen atom in the silacyclobutane substituent and complexation with NiCl2 proceed with retention of the silacyclobutane ring.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    N. V. Ushakov, E. L. Oshina & V. M. Vdovin

Authors
  1. N. V. Ushakov
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  2. E. L. Oshina
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  3. V. M. Vdovin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1906–1909, August, 1985.

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Ushakov, N.V., Oshina, E.L. & Vdovin, V.M. Reactions of 1-methyl-1-β-pyridyl-1-silacyclobutane with opening and retention of the silicon-carbon ring. Russ Chem Bull 34, 1756–1758 (1985). https://doi.org/10.1007/BF00948533

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  • DOI: https://doi.org/10.1007/BF00948533

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