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Transformed steroids. Communication 148. 1,3-Cycloaddition of diazomethane and diazoacetate to Δ15-17-ketoandrostane at normal and high pressures

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

1,3-Cycloaddition of diazomethane and ethyl diazoacetate to Δ15-17-ketoandrostane proceeds regio- and stereospecifically from the β-region of the steroid molecule, The pyrazolinoandrostanes obtained were converted into the corresponding 15β,16β-cyclopropane derivatives.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Kamernitskii, T. N. Galakhova, I. S. Levina, V. S. Él'yanov, V. S. Bodganov & E. G. Cherepanova

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  1. A. V. Kamernitskii
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  2. T. N. Galakhova
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  3. I. S. Levina
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  4. V. S. Él'yanov
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  5. V. S. Bodganov
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  6. E. G. Cherepanova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1893–1898, August, 1985.

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Kamernitskii, A.V., Galakhova, T.N., Levina, I.S. et al. Transformed steroids. Communication 148. 1,3-Cycloaddition of diazomethane and diazoacetate to Δ15-17-ketoandrostane at normal and high pressures. Russ Chem Bull 34, 1743–1748 (1985). https://doi.org/10.1007/BF00948530

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  • DOI: https://doi.org/10.1007/BF00948530

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