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Reaction of monovalent gold complex salts with ferrocene thio derivatives

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of 1,2,3-trithia[3]ferrocenophane with triphenylphosphinegold tetrafluoroborate leads to tris(triphenylphosphinegold)sulfonium tetrafluoroborate.

  2. 2.

    Relative to the auration of ethyl cyanoacetate, the aurating capacity of the tris-(triphenylphosphinegold)sulfonium tetrafluoroborate is significantly lower than that of (Ph3PAu)3O]+BF4 − and [(Ph3PAu)4N]+BF4 −.

  3. 3.

    The reaction of ferrocenylene-1,1′-dithiol with tris(triphenylphosphinegold)oxonium tetrafluoroborate gives (Ph3PAuSC5H4FeC5H4S)2.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    É. G. Perevalova, T. V. Baukova, M. M. Sazonenko & K. I. Grandberg

  2. M. V. Lomonosov Moscow State University, USSR

    É. G. Perevalova, T. V. Baukova, M. M. Sazonenko & K. I. Grandberg

Authors
  1. É. G. Perevalova
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  2. T. V. Baukova
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  3. M. M. Sazonenko
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  4. K. I. Grandberg
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1873–1876, August, 1985.

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Perevalova, É.G., Baukova, T.V., Sazonenko, M.M. et al. Reaction of monovalent gold complex salts with ferrocene thio derivatives. Russ Chem Bull 34, 1722–1726 (1985). https://doi.org/10.1007/BF00948525

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  • DOI: https://doi.org/10.1007/BF00948525

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