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Polarity and polarizability of some 1,4-dioxenes

  • A. A. Bredikhin
  • V. L. Polushina
  • A. N. Vereshchagin
Physical Chemistry
  • 23 Downloads

Conclusions

  1. 1.

    The dipole moments of the bonds and groups in the molecules of 1,4-dioxenes were determined.

     
  2. 2.

    The polarizability ellipsoids of the\(C_{sp^2 } - Cl\) and\(C_{sp^2 } - Br\) bonds and the effective polarizabiity ellipsoid of the\(C_{sp^2 } - O\) bond were determined in the series of halogen-substituted 1,4-dioxenes.

     
  3. 3.

    An equilibrium between the s-cis and s-trans conformations is realized in solutions of 2-formyldioxene. In 2,3-diphenyldioxene the planes of the phenyl substituents are orthogonal with the plane of the double bond.

     

Keywords

Phenyl Double Bond Dipole Moment Phenyl Substituent Polarizability Ellipsoid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • A. A. Bredikhin
    • 1
  • V. L. Polushina
    • 1
  • A. N. Vereshchagin
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' BranchAcademy of Sciences of the USSRUSSR

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