Catalytic activity of the products of low-temperature cocondensation of olefins with the vapors of transition metals

  • A. Yu. Vasil'kov
  • N. V. Zakurin
  • A. S. Kogan
  • V. A. Sergeev
  • G. V. Lisichkin
Organic Chemistry
  • 26 Downloads

Conclusions

  1. 1.

    The reaction of 1-hexene with vapors of Cr, Mn, Fe, Co, and Ni in the conditions of the method of high-vacuum, low-temperature cocondensation results in the formation of a suspension which is stable in an atmosphere of argon.

     
  2. 2.

    When the cocondensate is thawed, the starting 1-hexene undergoes catalytic transformations with the formation of products of positional and cis-, trans-isomerization, oligomerization, and dehydrocyclization.

     

Keywords

Atmosphere Argon Catalytic Activity Oligomerization Catalytic Transformation 

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • A. Yu. Vasil'kov
    • 1
  • N. V. Zakurin
    • 1
  • A. S. Kogan
    • 1
  • V. A. Sergeev
    • 1
  • G. V. Lisichkin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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