Conclusions
The previously unknown 9-vinyl- and 9-ethynyl-o- and m-carboranes were obtained by the reaction of vinyl- and ethynylmagnesium halides with 9-iodo-o- and 9-iodo-m-carboranes, catalyzed by palladium complexes.
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L. I. Zakharkin, A. I. Kovredov, V. A. Ol'shevskaya, and Zh. S. Shaugumbekova, Izv. Akad. Nauk SSSR, Ser. Khim., 1691 (1980).
L. I. Zakharkin, A. I. Kovredov, V. A. Ol'shevskaya, and Zh. S. Shaugumbekova, J. Organomet. Chem.,226, 217 (1982).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 888–892, April, 1985.
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Zakharkin, L.I., Kovredov, A.I. & Ol'shevskaya, V.A. Preparation of 9-vinyl-and 9-ethynyl-o-and m-carboranes. Russ Chem Bull 34, 809–812 (1985). https://doi.org/10.1007/BF00948065
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DOI: https://doi.org/10.1007/BF00948065