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Anisotropy of the magnetic susceptibility of the carbonyl group and molar cotton-mouton constants for aromatic aldehydes and ketones

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    From the molar Cotton-Mouton constants for acetone and cyclohexanone, we determined the magnetic susceptibility tensor for the C=O bond, which is paramagnetic in the plane of the carbonyl and diamagnetic in the perpendicular direction.

  2. 2.

    Within the framework of the tensor additive scheme, we calculated the theoretical molar Cotton-Mouton constants (which agree with experimental data) for aryl-containing aldehydes and ketones. This confirms the additive nature of the molecular magnetic susceptibility tensor for the studied compounds.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    S. G. Vul'fson, V. F. Nikolaev & A. N. Vereshchagin

Authors
  1. S. G. Vul'fson
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  2. V. F. Nikolaev
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  3. A. N. Vereshchagin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 809–814, April, 1985.

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Vul'fson, S.G., Nikolaev, V.F. & Vereshchagin, A.N. Anisotropy of the magnetic susceptibility of the carbonyl group and molar cotton-mouton constants for aromatic aldehydes and ketones. Russ Chem Bull 34, 732–737 (1985). https://doi.org/10.1007/BF00948047

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  • DOI: https://doi.org/10.1007/BF00948047

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