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Reaction of hexafluoroacetone benzenesulfonylimine with N-substituted carboxamides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Hexafluoroacetone benzenesulfonylimine reacts unambiguously with dimethylformamide, dimethylacetamide, and N-methylpyrrolidone to give the corresponding N-benzenesulfonylamidines and hexafluoroacetone.

  2. 2.

    2-Hydroxypyridine reacts with hexafluoroacetone benzenesulfonylimine the same as tertiary carboxylic acid amides to give 2-benzenesulfonylaminopyridine.

  3. 3.

    Some rules were ascertained for the transformation that take place in a system composed of hexafluoroacetone benzenesulfonylimine and carboxamides, and some theories were expressed regarding the mechanism of this reaction.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. V. Fokin, N. D. Chkanikov, V. L. Vershinin & A. F. Kolomiets

Authors
  1. A. V. Fokin
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  2. N. D. Chkanikov
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  3. V. L. Vershinin
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  4. A. F. Kolomiets
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 949–951, April, 1984.

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Fokin, A.V., Chkanikov, N.D., Vershinin, V.L. et al. Reaction of hexafluoroacetone benzenesulfonylimine with N-substituted carboxamides. Russ Chem Bull 33, 874–876 (1984). https://doi.org/10.1007/BF00947862

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  • DOI: https://doi.org/10.1007/BF00947862

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