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Reaction of η5-indenyltricarbonylrhenium with urotropin in ethanol, leading to rupture of C-C and O-H bonds in ethanol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When η5-C9H7Re(CO)3 is reacted with urotropin in ethanol, apparently as the result of rupture of the metal-π-ligand bond in C9H7Re(CO)3 and of the O-H and C-C bonds in ethanol, the N-methylurotropinium di(μ2-ethoxy)(μ2-methoxy)hexacarbonyldirhenate(1+) salt is formed, whose structure was proved by the RSA method.

  2. 2.

    η5-Indenyldicarbonyl(triisopropyl phosphite)rhenium was obtained.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. E. Kolobova, V. I. Zdanovich, I. A. Lobanova, V. G. Andrianov, Yu. T. Struchkov & P. V. Petrovskii

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  1. N. E. Kolobova
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  2. V. I. Zdanovich
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  3. I. A. Lobanova
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  4. V. G. Andrianov
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  5. Yu. T. Struchkov
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  6. P. V. Petrovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 945–948, April, 1984.

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Kolobova, N.E., Zdanovich, V.I., Lobanova, I.A. et al. Reaction of η5-indenyltricarbonylrhenium with urotropin in ethanol, leading to rupture of C-C and O-H bonds in ethanol. Russ Chem Bull 33, 871–874 (1984). https://doi.org/10.1007/BF00947861

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  • DOI: https://doi.org/10.1007/BF00947861

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